Details
High Quality Chinese Manufacturer supply 18666-68-7 TRIPHENYLVINYLSILANE
- Molecular Formula: C20H18Si
- Molecular Weight: 286.448
- Appearance/Colour: off-white to slightly beige crystalline powder
- Vapor Pressure: 3.2E-05mmHg at 25°C
- Melting Point: 68-70 °C(lit.)
- Refractive Index: 1.602
- Boiling Point: 365.9 °C at 760 mmHg
- Flash Point: 161.3 °C
- PSA： 0.00000
- Density: 1.04 g/cm3
- LogP: 2.88200
TRIPHENYLVINYLSILANE(Cas 18666-68-7) Usage
|
Purification Methods |
It has been recrystallised from EtOH, 95% EtOH, EtOH/*C6H6, pet ether (b 30-60o) and Et2O, and has been distilled under reduced pressure. [Cason & Brooks J Am Chem Soc 74 4582 1952, Nagel & Post J Org Chem 17 1379 1952, Beilstein 16 IV 1371.] |
InChI:InChI=1/C20H18Si/c1-2-21(18-12-6-3-7-13-18,19-14-8-4-9-15-19)20-16-10-5-11-17-20/h2-17H,1H2
18666-68-7 Relevant articles
CATALYST AND RELATED METHODS INVOLVING HYDROSILYLATION AND DEHYDROGENATIVE SILYLATION
-
Paragraph 00152-00154; 00157; 00160, (2019/02/06)
A catalyst having a specific structure a...
Fe and Co Complexes of Rigidly Planar Phosphino-Quinoline-Pyridine Ligands for Catalytic Hydrosilylation and Dehydrogenative Silylation
Basu, Debashis,Gilbert-Wilson, Ryan,Gray, Danielle L.,Rauchfuss, Thomas B.,Dash, Aswini K.
, p. 2760 - 2768 (2018/09/10)
Co and Fe dihalide complexes of a new ri...
Thieme Chemistry Journals Awardees - Where Are They Now? Titanium-Catalyzed Hydroaminoalkylation of Vinylsilanes and a One-Pot Procedure for the Synthesis of 1,4-Benzoazasilines
Lühning, Lars H.,Rosien, Michael,Doye, Sven
supporting information, p. 2489 - 2494 (2017/11/04)
Vinylsilanes undergo intermolecular alke...
Direct and selective arylation of tertiary silanes with rhodium catalyst
Yamanoi, Yoshinori,Nishihara, Hiroshi
, p. 6671 - 6678 (2008/12/22)
(Chemical Equation Presented) We have de...
18666-68-7 Process route
-
-
75-94-5
trichlorovinylsilane
-
-
18666-68-7
vinyltriphenylsilane
| Conditions | Yield |
|---|---|
|
With
phenylmagnesium bromide;
In
not given;
|
58%
|
|
With
C6H5MgBr;
In
not given;
|
58%
|
|
With
C6H5MgBr;
In
not given;
|
58%
|
-
-
74-85-1
ethene
-
-
789-25-3
HSiPh3
-
-
18666-68-7
vinyltriphenylsilane
| Conditions | Yield |
|---|---|
|
With
lithium triethylborohydride;
In
toluene;
at 70 ℃;
for 2h;
under 1520.1 Torr;
Reagent/catalyst;
Inert atmosphere;
Glovebox;
Schlenk technique;
|
95%
|
18666-68-7 Upstream products
-
75-94-5
trichlorovinylsilane
-
76-86-8
Triphenylsilyl chloride
-
3536-96-7
vinylmagnesium chloride
-
591-51-5
phenyllithium
18666-68-7 Downstream products
-
18849-30-4
(2-phenylethyl)triphenylsilane
-
18849-21-3
triphenyl[2-(phenylthio)ethyl]silane
-
18870-34-3
triphenyl-(2-p -tolylsulfanyl-ethyl)-silane
-
18870-33-2
2-benzylthioethyl-triphenylsilane
Related Products
-
Acorus calamus, ext.CAS：84775-39-3
-
-
(+)-LongifoleneCAS：475-20-7